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theoretical plasma spectroscopy A reliable plasma diagnostics requires both accurate measurements and solid theoretical support in interpretation of the experimental results. Since our primary experimental tool is spectroscopy (in other words, study of the light emitted by atoms or ions), our theorists try to understand what are the plasma conditions that bring about the measured light emission. Here they are developing a few directions in theoretical plasma spectroscopy:

Collisional-radiative (CR) calculations (Vladimir A. Bernshtam, Vladimir I. Fisher, Yuri V. Ralchenko, Alexander Starobinets)

This type of theoretical work explains how many photons leave the working volume during plasma evolution. This in turn depends on (i) probability of photon emission by an atom, (ii) how many atoms present in the upper (initial) state of radiative transition, and (iii) how many emitted photons are lost during their travel to the plasma boundary.

The first of these problems is solved with pure atomic theory. The plasma environment does affect the atom properties; however, in many cases its influence on photon emission probability is rather small and can therefore be neglected. Obviously, an access to and/or possibility to produce the reliable transition probabilities is of highest importance in the CR calculations.

In order to determine the number of atoms in specific states, one has to know what the kinetic processes affecting the atom states are and how they depend on plasma conditions. The kinetic processes, which are typically accounted for in CR calculations, are:

The rates of these processes depend on electron and atom energy distribution functions (mostly but not necessarily Maxwellian), and particle densities (both electron and atom).

The transport of photons through plasma volume is generally described by complicated radiative trasnfer equations. More simple methods are often used in practial calculations, for example, the so-called escape factor approximation.

We apply collisional-radiative modeling to study behavior of very diverse plasmas, such as those in Plasma Opening Switches, Z-pinches, X-ray lasers, etc.

Line broadening (Yuri V. Ralchenko, Evgeny Stambulchik)

Line spectra are affected by the motion of plasma particles (electrons, ions, and neutral species). Therefore, by measuring the spectral line shapes, it is possible to deduce such fundamental plasma parameters as temperature and density, as well as more involved characteristics like velocity distributions, presence of electric and magnetic fields etc.

The data derived from the spectral measurements, can be very complicated and, usually, there is no straightforward way to infer the plasma parameters directly. Thus, we need to be able to calculate the spectra either analythically or using computer simulations and then compare them to the observed data in order to determine plasma properties.

Hydrodynamic calculations (Vladimir I. Fisher)

Some insight in physics of Z-pinches and capillary discharges is provided by theoretical model which couples the electric circuit equation, two-temperature radiation magnetohydrodynamics (RMHD), and collisional-radiative (CR) kinetics of quantum states. The CR calculation of ionization composition in each plasma mass cell provides correct description of transport phenomena in non-equilibrium media. Direct account of unisotrpic radiation field in atomic kinetics allows for rigorous treatment of fine effects like lasing or pumping by external radiation source. At present, self-consistent calculations may by performed in 0-D approach only. The 1-D and 2-D versions of the model operate with some simplifications.